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  4. Thermodynamically stabilized beta-CsPbI3-based perovskite solar cells with efficiencies > 18%
 
research article

Thermodynamically stabilized beta-CsPbI3-based perovskite solar cells with efficiencies > 18%

Wang, Yong
•
Dar, M. Ibrahim  
•
Ono, Luis K.
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August 9, 2019
Science

Although beta-CsPbI3 has a bandgap favorable for application in tandem solar cells, depositing and stabilizing beta-CsPbI3 experimentally has remained a challenge. We obtained highly crystalline beta-CsPbI3 films with an extended spectral response and enhanced phase stability. Synchrotron-based x-ray scattering revealed the presence of highly oriented beta-CsPbI3 grains, and sensitive elemental analyses-including inductively coupled plasma mass spectrometry and time-of-flight secondary ion mass spectrometry-confirmed their all-inorganic composition. We further mitigated the effects of cracks and pinholes in the perovskite layer by surface treating with choline iodide, which increased the charge-carrier lifetime and improved the energy-level alignment between the beta-CsPbI3 absorber layer and carrier-selective contacts. The perovskite solar cells made from the treated material have highly reproducible and stable efficiencies reaching 18.4% under 45 +/- 5 degrees C ambient conditions.

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Type
research article
DOI
10.1126/science.aav8680
Web of Science ID

WOS:000483195200040

Author(s)
Wang, Yong
Dar, M. Ibrahim  
Ono, Luis K.
Zhang, Taiyang
Kan, Miao
Li, Yawen
Zhang, Lijun
Wang, Xingtao
Yang, Yingguo
Gao, Xingyu
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Date Issued

2019-08-09

Publisher

American Association for the Advancement of Science

Published in
Science
Volume

365

Issue

6453

Start page

591

End page

595

Subjects

Multidisciplinary Sciences

•

Science & Technology - Other Topics

•

total-energy calculations

•

open-circuit voltage

•

thin-films

•

phase

•

alpha-cspbi3

•

energetics

•

cspbl(3)

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
September 12, 2019
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/161118
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