CAN 147:406723

28-6

Heterocyclic Compounds (More Than One Hetero Atom)

National Laboratory for Molecular Sciences, Laboratory of Chemical Biology, Institute of Chemistry,Chinese Academy of Sciences,Beijing,Peop. Rep. China.

Journal

written in English.

7772-99-8 (Stannous chloride); 753001-91-1 Role: CAT (Catalyst use), USES (Uses) (catalyst comparison; chiral salen-aluminum complex as catalyst for enantioselective alpha -addn. of isocyanides to aldehydes providing 2-(1-hydroxyalkyl)-5-aminooxazoles); 78-84-2 (Isobutanal); 100-52-7 (Benzaldehyde); 104-88-1 (4-Chlorobenzaldehyde); 122-78-1 (Phenylacetaldehyde); 123-38-6 (Propanal); 135-02-4 (2-Methoxybenzaldehyde); 555-16-8 (4-Nitrobenzaldehyde); 630-19-3 (Pivalaldehyde); 2043-61-0 (Cyclohexanecarboxaldehyde); 3132-99-8 (3-Bromobenzaldehyde); 17407-55-5 ((2S)-2-Hydroxy-3-methylbutanoic acid); 56414-96-1 (2-Amino-1-(morpholino)ethanone); 60656-87-3 (2-(Benzyloxy)acetaldehyde); 67434-29-1 (2-Isocyano-1-(morpholin-4-yl)ethanone); 85059-48-9 (DL-2-Isocyano-1-(morpholin-4-yl)-3-phenyl-1-propanone); 500555-97-5 (N,N-Diethyl-2-isocyano-3-phenylpropanamide); 845791-23-3 (L-2-Isocyano-1-(morpholin-4-yl)-3-phenyl-1-propanone) Role: RCT (Reactant), RACT (Reactant or reagent) (chiral salen-aluminum complex as catalyst for enantioselective alpha -addn. of isocyanides to aldehydes providing 2-(1-hydroxyalkyl)-5-aminooxazoles); 951241-52-4P ((2S)-2-Hydroxy-3-methyl-N-[2-(morpholino)-2-oxoethyl]butanamide); 951241-53-5P ((S)-1-[4-Benzyl-5-(morpholin-4-yl)oxazol-2-yl]-2-methyl-1-propanol); 951241-54-6P ((S)-1-[4-Benzyl-5-(morpholin-4-yl)oxazol-2-yl]-1-propanol); 951241-55-7P ((S)-1-[4-Benzyl-5-(morpholin-4-yl)oxazol-2-yl]-2-phenylethanol); 951241-56-8P ((S)-4-Benzyl-5-(morpholin-4-yl)oxazol-2-ylmethanol); 951241-57-9P ((S)-1-[4-Benzyl-5-(morpholin-4-yl)oxazol-2-yl]-2,2-dimethyl-1-propanol); 951241-58-0P ((S)-1-[4-Benzyl-5-(morpholin-4-yl)oxazol-2-yl]-2-(benzyloxy)ethanol); 951241-59-1P ((S)-4-Benzyl-5-(morpholin-4-yl)oxazol-2-ylmethanol); 951241-60-4P ((S)-4-Benzyl-5-(morpholin-4-yl)oxazol-2-ylmethanol); 951241-61-5P ((S)-4-Benzyl-5-(morpholin-4-yl)oxazol-2-ylmethanol); 951241-62-6P ((S)-4-Benzyl-5-(morpholin-4-yl)oxazol-2-ylmethanol); 951241-63-7P ((S)-1-[4-Benzyl-5-(diethylamino)oxazol-2-yl]-2-methyl-1-propanol); 951241-64-8P ((S)-4-Benzyl-5-(diethylamino)oxazol-2-ylmethanol) Role: SPN (Synthetic preparation), PREP (Preparation) (chiral salen-aluminum complex as catalyst for enantioselective alpha -addn. of isocyanides to aldehydes providing 2-(1-hydroxyalkyl)-5-aminooxazoles); 96-10-6 (Chlorodiethylaluminum); 18531-94-7 ((R)-Binol); 20989-17-7 ((S)-2-Amino-2-phenylethanol); 62086-04-8; 128249-70-7 (2,6-Bis((4R)-4,5-dihydro-4-phenyloxazol-2-yl)pyridine) Role: CAT (Catalyst use), USES (Uses) (cocatalyst comparison; chiral salen-aluminum complex as catalyst for enantioselective alpha -addn. of isocyanides to aldehydes providing 2-(1-hydroxyalkyl)-5-aminooxazoles); 951241-65-9P ((S)-2-Methyl-1-[5-(morpholin-4-yl)oxazol-2-yl]-1-propanol) Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (hydrolysis; chiral salen-aluminum complex as catalyst for enantioselective alpha -addn. of isocyanides to aldehydes providing 2-(1-hydroxyalkyl)-5-aminooxazoles); 250611-13-3 Role: CAT (Catalyst use), USES (Uses) (preferred catalyst; chiral salen-aluminum complex as catalyst for enantioselective alpha -addn. of isocyanides to aldehydes providing 2-(1-hydroxyalkyl)-5-aminooxazoles)