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  4. Changes from Bulk to Surface Recombination Mechanisms between Pristine and Cycled Perovskite Solar Cells
 
research article

Changes from Bulk to Surface Recombination Mechanisms between Pristine and Cycled Perovskite Solar Cells

Correa-Baena, Juan -Pablo  
•
Turren-Cruz, Silver-Hamill
•
Tress, Wolfgang  
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2017
Acs Energy Letters

Several aspects on the photophysical characterization of lead halide hybrid organic inorganic perovskite solar cells remain unsolved. It has been observed that ionic transport and polarization of the interfaces cause very slow changes that interfere with transient measurements with effects that cannot be separated from recombination kinetics. Here we establish a protocol of initial measurement of the solar cell that provides information on recombination characteristics prior to applying any voltage cycling. The photovoltaic device is measured by several methods (photovoltage versus light intensity, open-circuit voltage decay, and impedance spectroscopy) while minimizing the exposure to external voltage stimulus to avoid ionic migration to the contacts. Results are independently confirmed by the analysis of samples with interdigitated electrodes. We show that the high-efficiency perovskite solar cells behave very closely to a bulk recombination ideal photovoltaic model. However, when voltage is scanned to determine current density voltage curves and impedance spectroscopy at fixed illumination intensity, the cell undergoes significant changes, which we attribute to a dominance of recombination at contacts that have been modified by ionic polarization. Our method provides an effective approach for determining quantitatively the rather significant changes that occur to perovskite solar cells during standard measurements, such as current voltage curves.

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Type
research article
DOI
10.1021/acsenergylett.7b00059
Web of Science ID

WOS:000396385000022

Author(s)
Correa-Baena, Juan -Pablo  
Turren-Cruz, Silver-Hamill
Tress, Wolfgang  
Hagfeldt, Anders  
Aranda, Clara
Shooshtari, Leyla
Bisquert, Juan
Guerrero, Antonio
Date Issued

2017

Publisher

Amer Chemical Soc

Published in
Acs Energy Letters
Volume

2

Issue

3

Start page

681

End page

688

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSPM  
Available on Infoscience
May 1, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/136854
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