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  4. Synthesis of carbonates and related compounds incorporating CO2 using ionic liquid-type catalysts: State-of-the-art and beyond
 
research article

Synthesis of carbonates and related compounds incorporating CO2 using ionic liquid-type catalysts: State-of-the-art and beyond

Bobbink, Felix D.  
•
Dyson, Paul J.  
2016
Journal Of Catalysis

The production of carbonates from carbon dioxide and epoxides is an atom-economical, scalable and industrially relevant reaction, highlighting the use of carbon dioxide as a sustainable source of carbon. Following a brief introduction on cyclic carbonates and their applications, the use of ionic liquids (ILs) as organocatalysts for the cycloaddition of CO2 to epoxides is analysed. Additionally, examples of one pot processes starting from alkenes or diols that may be used to produce carbonates are described (as these reactions are less developed the scope of the catalysts is not limited to IL catalysts). These alternatives are of special interest as simple alkenes and diols may be derived from biomass, leading to products derived entirely from renewable resources. (C) 2016 Elsevier Inc. All rights reserved.

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Type
research article
DOI
10.1016/j.jcat.2016.02.033
Web of Science ID

WOS:000387197600004

Author(s)
Bobbink, Felix D.  
Dyson, Paul J.  
Date Issued

2016

Publisher

Elsevier

Published in
Journal Of Catalysis
Volume

343

Start page

52

End page

61

Subjects

Sustainable chemistry

•

Carbon dioxide

•

Ionic liquids

•

Catalysis

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCOM  
Available on Infoscience
January 24, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/133715
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