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  4. Surface Chemistry Dictates the Enhancement of Luminescence and Stability of InP QDs upon c-ALD ZnO Hybrid Shell Growth
 
research article

Surface Chemistry Dictates the Enhancement of Luminescence and Stability of InP QDs upon c-ALD ZnO Hybrid Shell Growth

Lecina, Ona Segura
•
Newton, Mark Adrian  
•
Green, Philippe Benjamin  
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November 1, 2023
Jacs Au

Indium phosphide quantum dots (InP QDs) are a promising example of Restriction of Hazardous Substances directive (RoHS)-compliant light-emitting materials. However, they suffer from low quantum yield and instability upon processing under ambient conditions. Colloidal atomic layer deposition (c-ALD) has been recently proposed as a methodology to grow hybrid materials including QDs and organic/inorganic oxide shells, which possess new functions compared to those of the as-synthesized QDs. Here, we demonstrate that ZnO shells can be grown on InP QDs obtained via two synthetic routes, which are the classical sylilphosphine-based route and the more recently developed aminophosphine-based one. We find that the ZnO shell increases the photoluminescence emission only in the case of aminophosphine-based InP QDs. We rationalize this result with the different chemistry involved in the nucleation step of the shell and the resulting surface defect passivation. Furthermore, we demonstrate that the ZnO shell prevents degradation of the InP QD suspension under ambient conditions by avoiding moisture-induced displacement of the ligands from their surface. Overall, this study proposes c-ALD as a methodology for the synthesis of alternative InP-based core@shell QDs and provides insight into the surface chemistry that results in both enhanced photoluminescence and stability required for application in optoelectronic devices and bioimaging.

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Type
research article
DOI
10.1021/jacsau.3c00457
Web of Science ID

WOS:001096696800001

Author(s)
Lecina, Ona Segura
Newton, Mark Adrian  
Green, Philippe Benjamin  
Albertini, Petru Pasquale  
Leemans, Jari  
Marshall, Kenneth P.
Stoian, Dragos
Loiudice, Anna  
Buonsanti, Raffaella  
Date Issued

2023-11-01

Publisher

Amer Chemical Soc

Published in
Jacs Au
Subjects

Physical Sciences

•

Quantum Dots

•

Oxides

•

Hybrids

•

Core-Shell

•

Ligands

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LNCE  
FunderGrant Number

NCCR Catalysis

180544

Swiss National Science Foundation

Available on Infoscience
February 19, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/204149
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