Influence of Sphericity on Surface Termination of Icosahedral Colloidal Clusters
Colloids self-organize into icosahedral clusters composed of a Mackay core and an anti-Mackay shell under spherical confinement to minimize the free energy. This study explores the variation of surface arrangements of colloids in icosahedral clusters, focusing on the determining factors behind the surface arrangement. To efficiently assemble particles in emulsion droplets, droplet-to-droplet osmotic extraction from particle-laden droplets to salt-containing droplets is used, where the droplets are microfluidically prepared to guarantee a high size uniformity. The icosahedral clusters are optimally produced during a 24-h consolidation period at a 0.04 m salt concentration. The findings reveal an increase in the number of particle layers from 10 to 15 in the icosahedral clusters as the average number of particles increases from 3300 to 11 000. Intriguingly, the number of layers in the anti-Mackay shells, or surface termination, appears to more strongly depend on the sphericity of the clusters than on the deviation in the particle count from an ideal icosahedral cluster. This result suggests that the sphericity of the outermost layer, formed by the late-stage rearrangement of particles to form an anti-Mackay shell near the droplet interface, may play a pivotal role in determining the surface morphology to accommodate a spherical interface.|Icosahedral colloidal clusters are elaborately produced through a slow droplet-to-droplet osmotic extraction. The particle arrangement on the surface, determined by the layer number of the anti-Mackay shell, is more strongly influenced by the low sphericity than by the minimal deviation of the particle count from the magic number. This finding offers valuable insights into the particle assembly under spherical confinement.image
WOS:001118463800001
2023-12-10
REVIEWED
Funder | Grant Number |
Ministry of Science and ICT, South Korea | |
National Research Foundation of Korea | 2018M3A7B8060189 |