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review article

An experimentalist's guide to the matrix element in angle resolved photoemission

Moser, Simon  
2017
Journal Of Electron Spectroscopy And Related Phenomena

Angle resolved photoemission spectroscopy (ARPES) is commonly known as a powerful probe of the one-electron removal spectral function in ordered solid state. With increasing efficiency of light sources and spectrometers, experiments over a wide range of emission angles become more and more common. Consequently, the angular variation of ARPES spectral weight - often times termed "matrix element effect"- enters as an additional source of information. In this tutorial, we develop a simple but instructive free electron final state approach based on the three-step model to describe the intensity distribution in ARPES. We find a compact expression showing that the ARPES spectral weight of a given Bloch band is essentially determined by the momentum distribution (the Fourier transform) of its associated Wannier orbital - times a polarization dependent pre-factor. While the former is giving direct information on the symmetry and shape of the electronic wave function, the latter can give rise to surprising geometric effects. We discuss a variety of modern and instructive experimental showcases for which this simplistic formalism works astonishingly well and discuss the limits of this approach. (C) 2016 Elsevier B.V. All rights reserved.

  • Details
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Type
review article
DOI
10.1016/j.elspec.2016.11.007
Web of Science ID

WOS:000392037700004

Author(s)
Moser, Simon  
Date Issued

2017

Publisher

Elsevier Science Bv

Published in
Journal Of Electron Spectroscopy And Related Phenomena
Volume

214

Start page

29

End page

52

Subjects

ARPES

•

Intensity distribution

•

Matrix elements

•

Dichroism

•

Fourier transform

•

Tight binding

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSE  
Available on Infoscience
February 17, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/134570
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