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research article

Diffusivity and configurational entropy maxima in short range attractive colloids

Angelani, L.
•
Foffi, G.  
•
Sciortino, F.
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2005
Journal of Physics: Condensed Matter

We study tagged particle diffusion at large packing fractions, for a model of particles interacting with a generalized Lennard-Jones 2n-n potential, with large n. The resulting short range potential mimics interactions in colloidal systems. In agreement with previous calculations for short range potentials, we observe a diffusivity maximum as a function of temperature at constant density. By studying the temperature dependence of the configurational entropy which we evaluate with two different methods - we show that a configurational entropy maximum is observed at a temperature close to that of the diffusivity maximum. Our findings suggest a relation between the dynamics and number of distinct states for short range potentials. © 2005 IOP Publishing Ltd.

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Type
research article
DOI
10.1088/0953-8984/17/12/L02
Web of Science ID

WOS:000228616700002

Scopus ID

2-s2.0-16644394633

Author(s)
Angelani, L.
Foffi, G.  
Sciortino, F.
Tartaglia, P.
Date Issued

2005

Published in
Journal of Physics: Condensed Matter
Volume

17

Issue

12

Start page

L113

End page

L119

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GR-FO  
Available on Infoscience
January 27, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/46222
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