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  4. A Quasi-Solid-State Polymer Lithium-Metal Battery with Minimal Excess Lithium, Ultrathin Separator, and High-Mass Loading NMC811 Cathode
 
research article

A Quasi-Solid-State Polymer Lithium-Metal Battery with Minimal Excess Lithium, Ultrathin Separator, and High-Mass Loading NMC811 Cathode

Homann, Gerrit
•
Wang, Qing
•
Liu, Sufu
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October 31, 2024
ACS Applied Energy Materials

Solid-state batteries with lithium metal anodes are considered the next major technology leap with respect to today's lithium-ion batteries, as they promise a significant increase in energy density. Expectations for solid-state batteries from the automotive and aviation sectors are high, but their implementation in industrial production remains challenging. Here, we report a solid-state lithium-metal battery enabled by a polymer electrolyte consisting of a poly(DMADAFSI) cationic polymer and LiFSI in Pyr13FSI as plasticizer. The polymer electrolyte is infiltrated and solidified in the pores of a commercial LiNi0.8Mn0.1Co0.1O2 (NMC811) cathode with up to 2.8 mAh cm-2 nominal areal capacity and in the pores of a 25 mu m thin commercial polypropylene separator. Cathode and separator are finally laminated into a cell in combination with a commercial 20 mu m thin lithium metal anode. Our demonstration of a solid-state polymer battery cycling at full nominal capacity employing exclusively commercially available components available at industrial scale represents a critical step forward toward the commercialization of a competitive all-solid-state battery technology.

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Type
research article
DOI
10.1021/acsaem.4c02099
Web of Science ID

WOS:001345580500001

PubMed ID

39544916

Author(s)
Homann, Gerrit
•
Wang, Qing
•
Liu, Sufu
•
Devincenti, Antoine
•
Karanth, Pranav
•
Weijers, Mark
•
Mulder, Fokko M
•
Piesins, Matiss
•
Gouveia, Tom
•
LADAM, Alix
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Date Issued

2024-10-31

Publisher

AMER CHEMICAL SOC

Published in
ACS Applied Energy Materials
Volume

7

Issue

21

Start page

10037

End page

10043

Subjects

solid-state batteries

•

polymer

•

polymerizedionic liquid

•

thin lithium

•

high-mass-loading NMC811

•

infiltration

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
SMX-ENS  
FunderFunding(s)Grant NumberGrant URL

H2020 LEIT Advanced Materials

875557

European Union's Horizon 2020 research and innovation program for the Solidify project

European Union (EU)

875557

Available on Infoscience
January 28, 2025
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/245852
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