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  4. CuIn(1-x)Ga(x)Se2 photovoltaic devices for tandem solar cell application
 
research article

CuIn(1-x)Ga(x)Se2 photovoltaic devices for tandem solar cell application

Seyrling, S.
•
Calnan, S.
•
Bücheler, S.
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2009
Thin Solid Films

CuIn1-xGaxSe2 (CIGS) solar cells show a good spectral response in a wide range of the solar spectrum and the bandgap of CIGS can be adjusted from 1.0 eV to 1.7 eV by increasing the gallium-to-indium ratio of the absorber. While the bandgaps of Ga-rich CIGS or CGS devices make them suitable for top or intermediate cells, the In rich CIGS or CIS devices are well suited to be used as bottom cells in tandem solar cells. The photocurrent can be adapted to the desired value for current matching in tandem cells by changing the composition of CIGS which influences the absorption characteristics. Therefore, CIGS layers with different [Ga]/[In+Ga] ratios were grown on Mo and ZnO:Al coated glass substrates. The grain size, composition of the layers, and morphology strongly depend on the Ga content. Layers with Ga rich composition exhibit smaller grain size and poor photovoltaic performance. The current densities of CIGS solar cells on ZnO:Al/glass varied from 29 mA cm(-2) to 13 mA cm(-2) depending on the Ga content, and 13.5% efficient cells were achieved using a low temperature process (450 degrees C). However, Ga-rich solar cells exhibit lower transmission than dye sensitized solar cells (DSC). Prospects of tandem solar cells combining a DSC with CIGS are presented. (C) 2008 Elsevier B.V. All rights reserved.

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Type
research article
DOI
10.1016/j.tsf.2008.11.038
Web of Science ID

WOS:000263847300073

Author(s)
Seyrling, S.
Calnan, S.
Bücheler, S.
Hüpkes, J.
Wenger, S.  
Brémaud, D.
Zogg, H.
Tiwari, A.
Date Issued

2009

Published in
Thin Solid Films
Volume

517

Start page

2411

End page

2414

Subjects

Solar cells

•

CIGS

•

Tandem cells

•

Bandgap tuning

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
October 12, 2009
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/43656
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