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research article

Structure and rheology of star polymers in confined geometries: a mesoscopic simulation study

Zheng, Feiwo
•
Goujon, Florent
•
Mendonca, Ana C. F.
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2015
Soft Matter

Mesoscopic simulations of star polymer melts adsorbed onto solid surfaces are performed using the dissipative particle dynamics (DPD) method. A set of parameters is developed to study the low functionality star polymers under shear. The use of a new bond-angle potential between the arms of the star creates more rigid chains and discriminates between different functionalities at equilibrium, but still allows the polymers to deform appropriately under shear. The rheology of the polymer melts is studied by calculating the kinetic friction and viscosity and there is good agreement with experimental properties of these systems. The study is completed with predictive simulations of star polymer solutions in an athermal solvent.

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Type
research article
DOI
10.1039/c5sm01799h
Web of Science ID

WOS:000364824600004

Author(s)
Zheng, Feiwo
Goujon, Florent
Mendonca, Ana C. F.
Malfreyt, Patrice
Tildesley, Dominic J.  
Date Issued

2015

Publisher

Royal Soc Chemistry

Published in
Soft Matter
Volume

11

Issue

44

Start page

8590

End page

8598

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
ISIC-GE  
Available on Infoscience
February 16, 2016
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/123702
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