Practical guidance for obtaining optimum cis-selectivities in Wittig reactions with triphenylphosphonio-alkanides
The crucial role is played by the base, the solvent, and the temp. in detg. the stereochem. outcome of salt-free olefination reactions. Under optimized conditions unprecedented cis-selectivities are obsd. [on SciFinder (R)]
1986
40
7-8
244
245
CAN 106:33195 29-7 Organometallic and Organometalloidal Compounds Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz. Journal written in English. 67-56-1; 67-68-5; 75-65-0 (tert-Butyl alcohol); 7664-41-7 Role: USES (Uses) (Wittig reaction of triphenylphosphonioalkanides with aldehydes in presence of, regioselectivity in, reaction conditions in relation to); 999-97-3 Role: RCT (Reactant), RACT (Reactant or reagent) (Wittig reaction of triphenylphosphonioalkanides with aldehydes in presence of, regioselectivity in, reaction conditions in relation to); 109-72-8 (Butyllithium) Role: USES (Uses) (Wittig reaction of triphenylphosphonioalkanides with aldehydes in presence of, stereochem. in, reaction conditions in relation to); 108-94-1; 120-92-3; 502-42-1; 3487-44-3; 3728-50-5; 16666-78-7; 16666-80-1 Role: RCT (Reactant), RACT (Reactant or reagent) (Wittig reaction of, with aldehydes, stereochem. in, reaction conditions in relation to); 1754-88-7 Role: RCT (Reactant), RACT (Reactant or reagent) (Wittig reaction of, with aldehydes, stereoselectivity in, reaction conditions in relation to); 66-25-1; 100-52-7 Role: RCT (Reactant), RACT (Reactant or reagent) (Wittig reaction of, with triphenylphosphonioalkanides, stereochem. in, reaction conditions in relation to); 765-83-3; 766-90-5; 873-66-5; 1005-64-7; 1192-37-6; 1560-09-4; 2157-18-8; 2272-03-9; 2505-03-5; 7642-04-8; 7642-18-4; 13389-42-9; 16002-93-0; 20063-92-7; 20237-46-1; 53366-50-0 Role: RCT (Reactant), RACT (Reactant or reagent) (stereoselective formation of, in Wittig reaction of triphenylphosphonioalkanides with aldehydes, optimum conditions in relation to)
REVIEWED
EPFL