research article

Alcoholate Clusters ("Aggregates") and Their Role in Alkyne Forming Elimination Reactions

Schlosser, Manfred  
•
Tran Dinh, An
1981
Angewandte Chemie International Edition

Kinetic data for the dehydrochlorination of (E)- and (Z)-MeCH:CClC.tplbond.CCMe3 by KOCMe3 (I) in different solvents suggested that I assocs. participated in a push-pull, conveyor-belt mechanism. MeC.tplbond.CC.tplbond.CCMe3 was the only product from both olefin isomers. [on SciFinder (R)]

Type
research article
DOI
10.1002/anie.198110391
Author(s)
Schlosser, Manfred  
Tran Dinh, An
Date Issued

1981

Publisher

Wiley-VCH Verlag GmbH

Published in
Angewandte Chemie International Edition
Volume

20

Start page

1039

End page

1040

Subjects

Kinetics of dehydrochlorination (of chlorodimethylheptenyne by tert-butoxide); Dehydrochlorination (of chlorodimethylheptenyne by tert-butoxide

•

base aggregation in)

•

dehydrochlorination chlorodimethylheptenyne butoxide aggregate; heptenyne chlorodimethyl dehydrochlorination butoxide aggregate

Note

CAN 96:51537 22-4 Physical Organic Chemistry Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz. Journal 0044-8249 written in German. 79816-87-8; 79816-88-9 Role: RCT (Reactant), RACT (Reactant or reagent) (dehydrochlorination of, by tert-butoxide, aggregation of base in); 821-73-8P Role: FORM (Formation, nonpreparative), PREP (Preparation) (formation of, kinetics of)

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSCO  
Available on Infoscience
March 3, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/226798