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  4. Wafer-scale reliable switching memory based on 2-dimensional layered organic-inorganic halide perovskite
 
research article

Wafer-scale reliable switching memory based on 2-dimensional layered organic-inorganic halide perovskite

Seo, Ja-Young
•
Choi, Jaeho
•
Kim, Huo-Seon
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2017
Nanoscale

Recently, organic-inorganic halide perovskite (OHP) has been suggested as an alternative to oxides or chalcogenides in resistive switching memory devices due to low operating voltage, high ON/OFF ratio, and flexibility. The most studied OHP is 3-dimensional (3D) MAPbI(3). However, MAPbI(3) often exhibits less reliable switching behavior probably due to the uncontrollable random formation of conducting filaments. Here, we report the resistive switching property of 2-dimensional (2D) OHP and compare switching characteristics depending on structural dimensionality. The dimensionality is controlled by changing the composition of BA(2)MA(n-1)PbnI(3n+1) (BA = butylammonium, MA = methylammonium), where 2D is formed from n = 1, and 3D is formed from n = infinity. Quasi 2D compositions with n = 2 and 3 are also compared. Transition from a high resistance state (HRS) to a low resistance state (LRS) occurs at 0.25 x 10(6) V m(-1) for 2D BA(2)PbI(4) film, which is lower than those for quasi 2D and 3D. Upon reducing the dimensionality from 3D to 2D, the ON/OFF ratio significantly increases from 10(2) to 10(7), which is mainly due to the decreased HRS current. A higher Schottky barrier and thermal activation energy are responsible for the low HRS current. We demonstrate for the first time reliable resistive switching from 4 inch wafer-scale BA(2)PbI(4) thin film working at both room temperature and a high temperature of 87 degrees C, which strongly suggests that 2D OHP is a promising candidate for resistive switching memory.

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Type
research article
DOI
10.1039/c7nr05582j
Web of Science ID

WOS:000413905200005

Author(s)
Seo, Ja-Young
Choi, Jaeho
Kim, Huo-Seon
Kim, Jaegyeom
Yang, June-Mo
Cuhadar, Can
Han, Ji Su
Kim, Seung-Joo
Lee, Donghwa
Jang, Ho Won
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Date Issued

2017

Publisher

Royal Soc Chemistry

Published in
Nanoscale
Volume

9

Issue

40

Start page

15278

End page

15285

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
ISIC  
Available on Infoscience
December 4, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/142616
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