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  4. Unidirectional penetration approach for characterizing sulfate attack mechanisms on cement mortars and pastes
 
research article

Unidirectional penetration approach for characterizing sulfate attack mechanisms on cement mortars and pastes

Wang, Qiao  
•
Wilson, William  
•
Scrivener, Karen  
April 14, 2023
Cement and Concrete Research

Degradation of cementitious materials by sulfate ions is commonly classified into chemical and physical sulfate attack. So-called "physical" attack dominates in many field situations, but laboratory testing focuses on "chemical" attack under full-immersion. This paper presents a new setup which looks at sulfate ion ingress under unidirectional capillary action, as a first approach to field conditions. Here, a high concentration of sulfate ions and w/c and Portland cement were used to accelerate degradation to see if the approach is feasible. The radial expansion and appearance of mortar and paste samples were tracked over time. Periodically, profiles of sulfate ingress and phase assemblage were studied in the SEM and by X-ray diffraction. The results show that physical and chemical sulfate attack occur in different areas of the same sample. The approach shows potential to uncover the mechanisms involved in sulfate attack including both "chemical" and "physical" aspects of the degradation process.

  • Details
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Type
research article
DOI
10.1016/j.cemconres.2023.107166
Web of Science ID

WOS:000982873100001

Author(s)
Wang, Qiao  
Wilson, William  
Scrivener, Karen  
Date Issued

2023-04-14

Publisher

Pergamon-Elsevier Science Ltd

Published in
Cement and Concrete Research
Volume

169

Article Number

107166

Subjects

Construction & Building Technology

•

Materials Science, Multidisciplinary

•

Materials Science

•

chemical sulfate attack

•

physical sulfate attack

•

salt crystallization pressure

•

expansion

•

degradation

•

chemical profiles

•

phase profiles

•

sodium-sulfate

•

portland-cement

•

crystallization

•

concrete

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LMC  
Available on Infoscience
June 5, 2023
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/197923
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