research article

Experimental determination of the oscillator strength of the B(2B1)-X(2A2) transition of the free allyl radical

Van den Bergh, H. E.  
•
Callear, Anthony B.
1970
Transactions of the Faraday Society

The integrated absorption of the b1 - X transition of the Me radical (2160 .ANG.) and the B - X transition of the allyl radical (2100-2400 .ANG.) were compared, in the flash photolysis of 1-butene. From the f value of the Me band, the oscillator strength of the allyl transition was recorded as 0.140 (+-0.028). The rate coeff. for recombination of allyl radicals was in the range 8.5(+-3) * 1012 cm3 mole-1 sec-1.

Type
research article
DOI
10.1039/TF9706602681
Author(s)
Van den Bergh, H. E.  
Callear, Anthony B.
Date Issued

1970

Published in
Transactions of the Faraday Society
Volume

66

Start page

2681

End page

2684

Subjects

106-98-9 Role: RCT (Reactant)

•

RACT (Reactant or reagent) (photolysis of

•

flash); 1981-80-2; 2229-07-4 Role: PRP (Properties) (spectrum of

•

oscillator strengths of lines in uv)

•

allyl free radicals transitions; free radicals allyl transitions; radicals allyl transitions

Note

Copyright 2003 ACS

CAPLUS

AN 1970:535618

CAN 73:135618

73

Spectra by Absorption, Emission, Reflection, or Magnetic Resonance, and Other Optical Properties

Phys. Chem. Lab.,Cambridge,UK. FIELD URL:

Journal

TFSOA4

written in English.

Spectra (of allyl and methyl radicals, oscillator strengths of lines in); Kinetics of recombination (of allyl radicals); Photolysis (of butene)

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LPAS  
Available on Infoscience
February 1, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/63599