research article
Heptacoordinate Co-II Complex: A New Architecture for Photochemical Hydrogen Production
The first heptacoordinate cobalt catalyst for light-driven hydrogen production in water has been synthesized and characterized. Photochemical experiments using Ru(bpy)(3) as photosensitizer gave a turnover number (TON) of 16300molH(2)(molcat.)(-1) achieved in 2hours of irradiation with visible (475nm) light. This promising result provides a path forward in the development of new structures to improve the efficiency of the catalysis.
Type
research article
Web of Science ID
WOS:000401573100012
Author(s)
Lucarini, Fiorella
Pastore, Mariachiara
Vasylevskyi, Serhii
Varisco, Massimo
Solari, Euro
Crochet, Aurelien
Fromm, Katharina M.
Zobi, Fabio
Ruggi, Albert
Date Issued
2017
Publisher
Published in
Volume
23
Issue
28
Start page
6768
End page
6771
Editorial or Peer reviewed
REVIEWED
Written at
EPFL
EPFL units
Available on Infoscience
July 10, 2017
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