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  4. Heptacoordinate Co-II Complex: A New Architecture for Photochemical Hydrogen Production
 
research article

Heptacoordinate Co-II Complex: A New Architecture for Photochemical Hydrogen Production

Lucarini, Fiorella
•
Pastore, Mariachiara
•
Vasylevskyi, Serhii
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2017
Chemistry-A European Journal

The first heptacoordinate cobalt catalyst for light-driven hydrogen production in water has been synthesized and characterized. Photochemical experiments using Ru(bpy)(3) as photosensitizer gave a turnover number (TON) of 16300molH(2)(molcat.)(-1) achieved in 2hours of irradiation with visible (475nm) light. This promising result provides a path forward in the development of new structures to improve the efficiency of the catalysis.

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Type
research article
DOI
10.1002/chem.201701427
Web of Science ID

WOS:000401573100012

Author(s)
Lucarini, Fiorella
Pastore, Mariachiara
Vasylevskyi, Serhii
Varisco, Massimo
Solari, Euro
Crochet, Aurelien
Fromm, Katharina M.
Zobi, Fabio
Ruggi, Albert
Date Issued

2017

Publisher

Wiley-V C H Verlag Gmbh

Published in
Chemistry-A European Journal
Volume

23

Issue

28

Start page

6768

End page

6771

Subjects

cobalt

•

heptacoordinate complex

•

hydrogen

•

photocatalysis

•

polypyridyl ligand

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
ISIC  
Available on Infoscience
July 10, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/139132
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