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  4. Transmission electron microscopy study of the β′ phase (Al-Mg-Si alloys) and QC phase (Al-Cu-Mg-Si alloys): ordering mechanism and crystallographic structure
 
research article

Transmission electron microscopy study of the β′ phase (Al-Mg-Si alloys) and QC phase (Al-Cu-Mg-Si alloys): ordering mechanism and crystallographic structure

Buffat, PA  
•
Cayron, C.  
2000
Acta mater.

The β′ and QC rod-shaped precipitates, observed in the Al-Mg-Si and Al-Cu-Mg-Si alloys, respectively, are studied by transmission electron microscopy (TEM). Superstructure images and microdiffraction patterns confirm the likeness between the β′ and QC phases. The microdiffraction patterns are compared with computed ones in the aim to refine a previous structural model based on the existence of a latent disordered phase QP constituted by sub-unit triangular clusters. The space group of the β′ and QC phase is found to be hexagonal P6̄2m. Besides its smaller hexagonal parameter (a = 6.7 nm for QC and a = 0.71 nm for β′), the QC structure differs from the β′ one due to the Cu atoms contained in addition to the Si atoms in the triangular sites of the clusters. The phase transition of QC (or β′) from the latent phase QP (or βP) is concluded to be displacive. The complete phase transition (QP → QC → Q) or (βP → β′ → B′) during the elaboration of the materials is discussed.

  • Details
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Type
research article
DOI
10.1016/S1359-6454(00)00057-4
Author(s)
Buffat, PA  
Cayron, C.  
Date Issued

2000

Published in
Acta mater.
Volume

48

Issue

10

Start page

2639

End page

2653

Subjects

Aluminum alloys

•

Atoms

•

Clusters

•

Composition

•

Copper

•

Crystal lattices

•

High resolution electron microscopy

•

Microdiffraction pattern

•

Phase transitions

•

Precipitation (chemical)

•

Silicon

•

Transmission electron microscopy

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
CIME  
LMTM  
Available on Infoscience
February 15, 2007
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/2995
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