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  4. Pre-annealing for improved LPCVD deposited boron-doped poly-Si hole-selective contacts
 
research article

Pre-annealing for improved LPCVD deposited boron-doped poly-Si hole-selective contacts

Stuckelberger, Josua  
•
Yan, Di
•
Phang, Sieu Pheng
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March 1, 2023
Solar Energy Materials And Solar Cells

We demonstrate the beneficial effect of a pre-annealing step prior to the boron diffusion on passivation and contact resistivity of industrially LPCVD deposited poly-Si/SiOX hole-selective contacts. We investigate the influence of the pre-annealing temperature on passivation quality, measured as implied open-circuit voltage and recombination current density, and on changes in crystallinity, characterized by Raman spectroscopy. A clear increase in passivation quality is observed on planar and textured surfaces as well as for various poly-Si thicknesses (100-230 nm) and thermal SiOX growth temperatures (600-800 degrees C). On planar surfaces and without the use of atomic hydrogenation, we report an increase in iVOC of around 5 mV with every additional increase of pre-annealing temperature by 50 degrees C (>900 degrees C) leading to an iVOC of 720 mV (J0 = 9.3 fA/cm2). After atomic hydrogenation, the effect of the pre-annealing is less pronounced. Nevertheless a gain in iVOC (reduction in J0) of 5-10 mV (2-5 fA/cm2) is achieved when comparing samples without pre-annealing with samples after a pre-annealing at 1050 degrees C. On textured surfaces on the other hand, this trend is more pronounced after atomic hydrogenation, for which a pre-crystallisation at 1050 degrees C leads to an iVOC (J0) of 705 mV (16.8 fA/cm2), which is a gain (reduction) of 24 mV (21.7 fA/cm2) compared to samples without a pre-annealing step.

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Type
research article
DOI
10.1016/j.solmat.2022.112123
Web of Science ID

WOS:000990599200001

Author(s)
Stuckelberger, Josua  
Yan, Di
Phang, Sieu Pheng
Samundsett, Chris
Wang, Jiali
Antognini, Luca  
Haug, Franz-Josef  
Wang, Zhao
Yang, Jie
Zheng, Peiting
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Date Issued

2023-03-01

Publisher

ELSEVIER

Published in
Solar Energy Materials And Solar Cells
Volume

251

Article Number

112123

Subjects

Energy & Fuels

•

Materials Science, Multidisciplinary

•

Physics, Applied

•

Materials Science

•

Physics

•

rear contacts

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solar-cells

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microcrystalline silicon

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structural-properties

•

passivation quality

•

polysilicon

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diffusion

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temperature

•

transition

•

resistance

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

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PV-LAB  
Available on Infoscience
June 5, 2023
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/198026
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