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research article

New method for lateral mapping of bimolecular recombination in thin-film organic solar cells

Bergqvist, Jonas
•
Tress, Wolfgang  
•
Forchheimer, Daniel
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2016
Progress In Photovoltaics

The best organic solar cells are limited by bimolecular recombination. Tools to study these losses are available; however, they are only developed for small area (laboratory-scale) devices and are not yet available for large area (production-scale) devices. Here we introduce the Intermodulation Light Beam-Induced Current (IMLBIC) technique, which allows simultaneous spatial mapping of both the amount of extracted photocurrent and the bimolecular recombination over the active area of a solar cell. We utilize the second-order non-linear dependence on the illumination intensity as a signature for bimolecular recombination. Using two lasers modulated with different frequencies, we record the photocurrent response at each modulation frequency and the bimolecular recombination in the second-order intermodulation response at the sum and difference of the two frequencies. Drift-diffusion simulations predict a unique response for different recombination mechanisms. We successfully verify our approach by studying solar cells known to have mainly bimolecular recombination and thus propose this method as a viable tool for lateral detection and characterization of the dominant recombination mechanisms in organic solar cells. We expect that IMLBIC will be an important future tool for characterization and detection of recombination losses in large area organic solar cells. Copyright (c) 2016 John Wiley & Sons, Ltd.

  • Details
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Type
research article
DOI
10.1002/pip.2770
Web of Science ID

WOS:000380164100007

Author(s)
Bergqvist, Jonas
Tress, Wolfgang  
Forchheimer, Daniel
Melianas, Armantas
Tang, Zheng
Haviland, David
Inganas, Olle
Date Issued

2016

Publisher

Wiley-Blackwell

Published in
Progress In Photovoltaics
Volume

24

Issue

8

Start page

1096

End page

1108

Subjects

organic photovoltaics

•

imaging

•

photocurrent

•

bimolecular recombination

•

light beam-induced current

•

LBIC

•

intermodulation

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
October 18, 2016
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/130434
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