Effect of periodic process execution on radical polymerizations
In the free-radical polymn. of styrene, a pulsed- or batch-type of polymn. process gave a higher space-time yield and efficiency than a stationary process at the same product mol. wt. and polydispersity. In the batch process, the range of av. mol. wt., conversion, and polydispersity fell between the values for a stationary process at the same concn. and one at a doubled concn. [on SciFinder (R)]
1979
51
1
42
3
u'CAN 90:104405', u'35-3', u'Synthetic High Polymers', u'Inst. Genie Chim.,Eidg. Tech. Hochsch.,Hannover,Fed. Rep. Ger.', u'Journal', u'0009-286X', u'written in German (Der Einfluß periodischer Prozeßführung auf radikalische Polymerisationsreaktionen) u'9003-53-6P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of, by batch process, efficiency and yields in)'
REVIEWED
EPFL