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review article

Water-Mediated Ion Pairing: Occurrence and Relevance

Van Der Vegt, Nico F. A.
•
Haldrup, Kristoffer
•
Roke, Sylvie  
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2016
Chemical Reviews

We present an overview of the studies of ion pairing in aqueous media of the past decade. In these studies, interactions between ions, and between ions and water, are investigated with relatively novel approaches, including dielectric relaxation spectroscopy, far-infrared (terahertz) absorption spectroscopy, femtosecond mid infrared spectroscopy, and X-ray spectroscopy and scattering, as well as molecular dynamics simulation methods. With these methods, it is found that ion pairing is not a rare phenomenon only occurring for very particular, strongly interacting cations and anions. Instead, for many salt solutions and their interfaces, the measured and calculated structure and dynamics reveal the presence of a distinct concentration of contact ion pairs (CIPs), solvent shared ion pairs (SIPs), and solvent-separated ion pairs (2SIPs). We discuss the importance of specific ion-pairing interactions between cations like Li+ and Na+ and anionic carboxylate and phosphate groups for the structure and functioning of large (bio)molecular systems.

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Type
review article
DOI
10.1021/acs.chemrev.5b00742
Web of Science ID

WOS:000379794000009

Author(s)
Van Der Vegt, Nico F. A.
Haldrup, Kristoffer
Roke, Sylvie  
Zheng, Junrong
Lund, Mikael
Bakker, Huib J.
Date Issued

2016

Publisher

American Chemical Society

Published in
Chemical Reviews
Volume

116

Issue

13

Start page

7626

End page

7641

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LBP  
Available on Infoscience
October 18, 2016
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/129820
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