Publication: Ruthenium-based metallacrown complexes for the selective detection of lithium ions in water and in serum by fluorescence spectroscopy
Ruthenium-based metallacrown complexes for the selective detection of lithium ions in water and in serum by fluorescence spectroscopy
| cris.lastimport.scopus | 2024-08-05T03:59:12Z | |
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| cris.virtual.department | LCS | |
| cris.virtual.parent-organization | ISIC | |
| cris.virtual.parent-organization | SB | |
| cris.virtual.parent-organization | EPFL | |
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| cris.virtual.unitManager | Severin, Kay | |
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| datacite.rights | restricted | |
| dc.contributor.author | Rochat, Sébastien | |
| dc.contributor.author | Grote, Zacharias | |
| dc.contributor.author | Severin, Kay | |
| dc.date.accessioned | 2009-03-05T13:58:29 | |
| dc.date.created | 2009-03-05 | |
| dc.date.issued | 2009 | |
| dc.date.modified | 2025-01-23T17:02:35.046635Z | |
| dc.description.abstract | Fluorescent dihydroxypyridine ligands were prepared by attaching pyrene-, dansyl-, and methoxycoumarin-fluorophores via dimethyleneamine linkers. The reaction of these ligands with [(p-cymene)RuCl2]2 or [(C6H5CH2NMe2H)RuCl2]2Cl2 resulted in the formation of 12-metallacrown-3 complexes, which possess strong affinity for lithium ions. By a judicious choice of the fluorophore and the arene -ligand, a macrocycle was obtained that could be used in aqueous solution to selectively and quantitatively detect lithium ions by fluorescence spectroscopy | |
| dc.description.sponsorship | LCS | |
| dc.identifier.doi | 10.1039/b820592b | |
| dc.identifier.isi | WOS:000263922700016 | |
| dc.identifier.uri | ||
| dc.relation | https://infoscience.epfl.ch/record/134604/files/OBC-2009-Rochat.pdf | |
| dc.relation.journal | ORGANIC & BIOMOLECULAR CHEMISTRY | |
| dc.subject | Supramolecular Triangular Hosts | |
| dc.subject | Amyotrophic-Lateral-Sclerosis | |
| dc.subject | 12-Metallacrown-3 Complexes | |
| dc.subject | Alzheimers-Disease | |
| dc.subject | Li+ | |
| dc.subject | Sensor | |
| dc.subject | Recognition | |
| dc.subject | Fluoroionophore | |
| dc.subject | Extraction | |
| dc.subject | Stability | |
| dc.title | Ruthenium-based metallacrown complexes for the selective detection of lithium ions in water and in serum by fluorescence spectroscopy | |
| dc.type | text::journal::journal article::research article | |
| dspace.entity.type | Publication | |
| dspace.legacy.oai-identifier | oai:infoscience.tind.io:134604 | |
| epfl.legacy.fileversion | n/a | |
| epfl.legacy.itemtype | Journal Articles | |
| epfl.legacy.submissionform | ARTICLE | |
| epfl.oai.currentset | SB | |
| epfl.oai.currentset | OpenAIREv4 | |
| epfl.oai.currentset | article | |
| epfl.peerreviewed | REVIEWED | |
| epfl.publication.version | ||
| epfl.writtenAt | EPFL | |
| oaire.citation.endPage | 1153 | |
| oaire.citation.startPage | 1147 | |
| oaire.citation.volume | 7 |