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research article

The influence of viscosity on the liquid-phase mass transfer resistance in packed columns

Delaloye, Maurice M.
•
Von Stockar, Urs  
•
Lu, Xiaoping
1991
Chemical Engineering Journal

The correlations available in the literature cannot be used to est. the liq.-phase mass-transfer coeff. (kL) for viscous solns. Even correlations that agree for water-like viscosities diverge by an order of magnitude for viscosities of only 10 mPa-s. Here, kL (kLa) measurements are given that are performed by stripping O from aq. solns. in a column of 0.3-m diam. filled with 0.025-m glass Raschig rings. The viscosity is varied by varying the amt. of Na alginate, glycerol, or polyethylene glycol in the water. The viscosity not only has an effect on the diffusivity of the absorbed gas (this highlights the importance of accurate diffusivity estns., both for data interpretation and for design work), but also has an addnl. net effect such that kLa/D1/2 (D = diffusivity of solute in liq.) decreases in approx. inverse proportion to the square root of the viscosity. [on SciFinder (R)]

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Type
research article
DOI
10.1016/0300-9467(91)85007-I
Author(s)
Delaloye, Maurice M.
•
Von Stockar, Urs  
•
Lu, Xiaoping
Date Issued

1991

Published in
Chemical Engineering Journal
Volume

47

Issue

1

Start page

51

End page

61

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LGCB  
Available on Infoscience
February 27, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/225962
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