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Origin of apparent light-enhanced and negative capacitance in perovskite solar cells

Ebadi, Firouzeh
•
Taghavinia, Nima
•
Mohammadpour, Raheleh
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April 5, 2019
Nature Communications

So-called negative capacitance seems to remain an obscure feature in the analysis of the frequency-dependent impedance of perovskite solar cells. It belongs to one of the puzzling peculiarities arising from the mixed ionic-electronic conductivity of this class of semiconductor. Here we show that apparently high capacitances in general (positive and negative) are not related to any capacitive feature in the sense of a corresponding charge accumulation. Instead, they are a natural consequence of slow transients mainly in forward current of the diode upon ion displacement when changing voltage. The transient current leads to a positive or negative 'capacitance' dependent on the sign of its gradient. The 'capacitance' appears so large because the associated resistance, when thinking of a resistor-capacitor element, results from another physical process, namely modified electronic charge injection and transport. Observable for a variety of devices, it is a rather universal phenomenon related to the hysteresis in the current-voltage curve.

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s41467-019-09079-z.pdf

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http://purl.org/coar/version/c_970fb48d4fbd8a85

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