Loading...
research article
Configurational entropy of hard spheres
We numerically calculate the configurational entropy Sconf of a binary mixture of hard spheres, by using a perturbed Hamiltonian method trapping the system inside a given state, which requires fewer assumptions than the previous methods (Speedy 1998 Mol.Phys. 95 169). We find that Sconf is a decreasing function of the packing fraction φ and extrapolates to zero at the Kauzmann packing fraction , suggesting the possibility of an ideal glass transition for the hard-sphere system. Finally, the Adam-Gibbs relation is found to hold. © IOP Publishing Ltd.
Type
research article
Web of Science ID
WOS:000247074800025
Scopus ID
2-s2.0-34250209183
Authors
Publication date
2007
Published in
Volume
19
Issue
25
Article Number
256207
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
January 27, 2010
Use this identifier to reference this record