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research article

Configurational entropy of hard spheres

Angelani, L.
•
Foffi, G.  
2007
Journal of Physics: Condensed Matter

We numerically calculate the configurational entropy Sconf of a binary mixture of hard spheres, by using a perturbed Hamiltonian method trapping the system inside a given state, which requires fewer assumptions than the previous methods (Speedy 1998 Mol.Phys. 95 169). We find that Sconf is a decreasing function of the packing fraction φ and extrapolates to zero at the Kauzmann packing fraction , suggesting the possibility of an ideal glass transition for the hard-sphere system. Finally, the Adam-Gibbs relation is found to hold. © IOP Publishing Ltd.

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Type
research article
DOI
10.1088/0953-8984/19/25/256207
Web of Science ID

WOS:000247074800025

Scopus ID

2-s2.0-34250209183

Author(s)
Angelani, L.
Foffi, G.  
Date Issued

2007

Published in
Journal of Physics: Condensed Matter
Volume

19

Issue

25

Article Number

256207

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GR-FO  
Available on Infoscience
January 27, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/46218
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