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  4. Light emission properties of mechanical exfoliation induced extended defects in hexagonal boron nitride flakes
 
research article

Light emission properties of mechanical exfoliation induced extended defects in hexagonal boron nitride flakes

Ciampalini, G.
•
Blaga, C., V
•
Tappy, N.
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July 1, 2022
2D Materials

Recently, hexagonal boron nitride (hBN) has become an interesting platform for quantum optics due to its peculiar defect-related luminescence properties. Concomitantly, hBN was established as the ideal insulating support for realizing 2D materials devices, where, on the contrary, defects can affect the device performance. In this work, we study the light emission properties of hBN flakes obtained by mechanical exfoliation with particular focus on extended defects generated in the process. In particular, we tackle different issues related to the light emission in hBN flakes of different thicknesses in the range of hundreds of nanometers, revealing a higher concentration of deep level emission in thinner area of the flake. We recognize the effect of crystal deformation in some areas of the flake with an important blue-shift (130 meV) of the room temperature near band edge emission of hBN and the concurrent presence of a novel emission at 2.36 eV, related to the formation of array of dislocations. We studied the light emission properties by means of cathodoluminescence (CL) and sub-bandgap excitation photoluminescence of thickness steps with different crystallographic orientations, revealing the presence of different concentration of radiative centers. CL mapping allows to detect buried thickness steps, invisible to the scanning electron microscopy and atomic force microscopy morphological analysis.

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Type
research article
DOI
10.1088/2053-1583/ac6f09
Web of Science ID

WOS:000812409600001

Author(s)
Ciampalini, G.
Blaga, C., V
Tappy, N.
Pezzini, S.
Watanabe, K.
Taniguchi, T.
Bianco, F.
Roddaro, S.
Morral, A. Fontcuberta, I  
Fabbri, F.
Date Issued

2022-07-01

Publisher

IOP Publishing Ltd

Published in
2D Materials
Volume

9

Issue

3

Article Number

035018

Subjects

Materials Science, Multidisciplinary

•

Materials Science

•

hexagonal boron nitride

•

extended defects

•

mechanical exfoliation

•

optical properties

•

der-waals heterostructures

•

electron-microscopy

•

quantum emitters

•

emitting-diodes

•

high-quality

•

graphene

•

bn

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LMSC1  
Available on Infoscience
July 4, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/189013
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