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research article
Why are (NN2)Ni pincer complexes active for alkyl-alkyl coupling: ß-H elimination is kinetically accessible but thermodynamically uphill
2010
Isomerization and olefin exchange experiments show that β-H elimination is kinetically viable but thermodynamically unfavorable in [(MeNN2)Ni-alkyl] complexes. The intermediacy of Ni-hydride species was corroborated by a trapping experiment. The alkyl complex [(MeNN2)Ni-propyl] catalyzes olefin isomerization.
Type
research article
Web of Science ID
WOS:000281472500002
Publication date
2010
Publisher
Published in
Volume
29
Issue
17
Start page
3686
End page
3689
Peer reviewed
REVIEWED
Written at
EPFL
Available on Infoscience
August 12, 2010
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