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  4. Pizza Oven Processing of Organohalide Perovskites (POPOP): A Simple, Versatile and Efficient Vapor Deposition Method
 
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research article

Pizza Oven Processing of Organohalide Perovskites (POPOP): A Simple, Versatile and Efficient Vapor Deposition Method

Guesnay, Quentin Jean-Marie Armand  
•
Sahli, Florent
•
Artuk, Kerem  
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February 2, 2024
Advanced Energy Materials

Hybrid vapor deposition is one of the most appealing processes for perovskite photovoltaics fabrication, thanks to its versatile nature. By using sequentially different vapor deposition processes tailored to the inorganic and organic perovskite precursors' peculiarities, this type of process gives access to the full potential of vapor deposition. While vapor deposition of metal halides is well understood and mastered, vapor deposition of organohalide species is much more delicate (degradation of vapors, high vapor pressure, setup-specific constraints). Here, a novel close space sublimation system is reported and in-depth insights on the conversion into perovskite of a metal halide template are provided. In this evolution of the process, the substrate coated with metal halide template and the organohalide source are loaded together in a dedicated holder, then transferred into a vacuum chamber on a heating element already at temperature setpoint. The system enables a simple, fast, low-cost, and easy-to-reproduce organohalide vapor deposition process. The formation of the perovskite in situ and identification different conversion regimes are studied. Furthermore, the influence of the chemical environment and chamber design on the process are discussed. Compositional tuning and additive engineering in the process are processed and fabricate proof of concept photovoltaic devices reaching high fill factors of 80% and 17% power conversion efficiency for a bandgap of 1.63 eV.

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Type
research article
DOI
10.1002/aenm.202303423
Web of Science ID

WOS:001155955500001

Author(s)
Guesnay, Quentin Jean-Marie Armand  
•
Sahli, Florent
•
Artuk, Kerem  
•
Turkay, Deniz  
•
Kuba, Austin George  
•
Mrkyvkova, Nada
•
Vegso, Karol
•
Siffalovic, Peter
•
Schreiber, Frank
•
Lai, Huagui
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Date Issued

2024-02-02

Publisher

Wiley-V C H Verlag Gmbh

Published in
Advanced Energy Materials
Subjects

Physical Sciences

•

Technology

•

In Situ Giwaxs & Pl

•

Nmr

•

Organohalides

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Perovskite Growth

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Perovskite

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Photovoltaics

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Plqy

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Thin Films

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Tof Sims

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Vapor Deposition

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
PV-LAB  
FunderGrant Number

Horizon 2020

101006715

European Union

200021_197006

Swiss National Science Foundation

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Available on Infoscience
February 23, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/205473
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