Publication: Catalytic Activity of Bis-phosphine Ruthenium(II)-Arene Compounds: Chemoselective Hydrogenation and Mechanistic Insights
Catalytic Activity of Bis-phosphine Ruthenium(II)-Arene Compounds: Chemoselective Hydrogenation and Mechanistic Insights
| cris.lastimport.scopus | 2024-08-09T10:41:35Z | |
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| cris.virtual.parent-organization | EPFL | |
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| cris.virtual.unitManager | Dyson, Paul Joseph | |
| cris.virtual.unitManager | Vittoria Belmondo | |
| cris.virtual.unitManager | Dyson, Paul Joseph | |
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| datacite.rights | metadata-only | |
| dc.contributor.author | Chaplin, AB | |
| dc.contributor.author | Dyson, PJ | |
| dc.date.accessioned | 2007-11-09T17:53:25 | |
| dc.date.available | 2007-11-09T17:53:25 | |
| dc.date.created | 2007-11-09 | |
| dc.date.issued | 2007 | |
| dc.date.modified | 2025-05-06T07:27:49.295108Z | |
| dc.description.abstract | Bis-phosphine Ru(II)-arene complexes are highly active and chemoselective catalysts for the hydrogenation of aldehydes in the presence of olefinic bonds. Mechanistic studies, including comparisons with a structural analog, reactions of an isolated hydride complex, base poisoning expts., and a computational anal., help rationalize the preferential hydrogenation of C=O bonds, which probably proceeds via an ionic outer-sphere mechanism. | |
| dc.description.sponsorship | LCOM | |
| dc.identifier.doi | 10.1021/om7005112 | |
| dc.identifier.uri | ||
| dc.relation.journal | Organometallics | |
| dc.title | Catalytic Activity of Bis-phosphine Ruthenium(II)-Arene Compounds: Chemoselective Hydrogenation and Mechanistic Insights | |
| dc.type | text::journal::journal article::research article | |
| dspace.entity.type | Publication | |
| dspace.legacy.oai-identifier | oai:infoscience.tind.io:113996 | |
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| epfl.legacy.itemtype | Journal Articles | |
| epfl.legacy.submissionform | ARTICLE | |
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| epfl.oai.currentset | OpenAIREv4 | |
| epfl.oai.currentset | article | |
| epfl.peerreviewed | REVIEWED | |
| epfl.publication.version | ||
| epfl.writtenAt | EPFL | |
| oaire.citation.endPage | 4360 | |
| oaire.citation.issue | 17 | |
| oaire.citation.startPage | 4357 | |
| oaire.citation.volume | 26 |
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