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  4. Local resilience of the 1T-TiSe2 charge density wave to Ti self-doping
 
research article

Local resilience of the 1T-TiSe2 charge density wave to Ti self-doping

Hildebrand, B.
•
Jaouen, T.
•
Didiot, C.
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2017
Physical Review B

In Ti-intercalated self-doped 1T-TiSe2 crystals, the charge density wave (CDW) superstructure induces two nonequivalent sites for Ti dopants. Recently, it has been shown that increasing Ti doping dramatically influences the CDW by breaking it into phase-shifted domains. Here, we report scanning tunneling microscopy and spectroscopy experiments that reveal a dopant-site dependence of the CDW gap. Supported by density functional theory, we demonstrate that the loss of the long-range phase coherence introduces an imbalance in the intercalated-Ti site distribution and restrains the CDW gap closure. This local resilient behavior of the 1T-TiSe2 CDW reveals an entangled mechanism between CDW, periodic lattice distortion, and induced nonequivalent defects.

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Type
research article
DOI
10.1103/PhysRevB.95.081104
Web of Science ID

WOS:000402193100002

Author(s)
Hildebrand, B.
Jaouen, T.
Didiot, C.
Razzoli, E.
Monney, G.
Mottas, M. -L.
Vanini, F.
Barreteau, C.
Ubaldini, A.
Giannini, E.
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Date Issued

2017

Publisher

Amer Physical Soc

Published in
Physical Review B
Volume

95

Issue

8

Article Number

081104

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSE  
Available on Infoscience
July 10, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/139177
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