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research article

Lennard-Jones binary mixture in disordered matrices: exploring the mode coupling scenario at increasing confinement

Gallo, P.
•
Rovere, M.
2011
Journal of Physics: Condensed Matter

We present results of molecular dynamics simulations performed on a Lennard-Jones liquid binary mixture confined in matrices of soft spheres at increasing packing fraction. We study the dynamical properties of the liquid at a given density upon supercooling. Our aim is to test the validity of the mode coupling theory in predicting the behaviour of the glass forming liquid when it is under confinement in a disordered matrix. We use two different methods to build up the confining environment. We focus in particular on the behaviour of the single particle density correlators. We find a close agreement with the mode coupling theory at least for all the range of packing fractions examined. Discrepancies between the theory and the computer simulation results can be attributed to hopping effects which are more important at increasing confinement.

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Type
research article
DOI
10.1088/0953-8984/23/23/234118
Web of Science ID

WOS:000290957300021

Author(s)
Gallo, P.
Rovere, M.
Date Issued

2011

Published in
Journal of Physics: Condensed Matter
Volume

23

Issue

23

Article Number

234118

Subjects

Glass-Transition

•

Computer-Simulations

•

Relaxation Dynamics

•

Micellar System

•

Random-Media

•

Liquid

•

Fluids

•

Crossover

•

Water

•

Bulk

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
SB  
Available on Infoscience
December 16, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/74053
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