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  4. Dynamics across the structural transitions at elevated temperatures in Na0.7CoO2
 
conference paper

Dynamics across the structural transitions at elevated temperatures in Na0.7CoO2

Juranyi, Fanni
•
Mansson, Martin  
•
Gavilano, Jorge L.
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Frick, B
•
Koza, Mm
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2015
Qens/Wins 2014 - 11Th International Conference On Quasielastic Neutron Scattering And 6Th International Workshop On Inelastic Neutron Spectrometers
11th International Conference on Quasielastic Neutron Scattering / 6th International Workshop on Inelastic Neutron Spectrometers (QENS/WINS)

The layered transition-metal oxide Nax CoO2 has been studied extensively both for its correlated electronic properties as well as for potential battery applications. It was discovered that high-temperature Na ion vacancy order and dynamics can be very useful to tailor low-temperature properties of members of this compound family. We have studied the Na-ion dynamics on the atomic length-scale in the Na-0.7 CoO2 compound by neutron spectroscopy. The temperature dependence of both the elastic and the inelastic intensities show steps at T-A approximate to 290K and T-B approximate to 400 K. At T-A the step is shown to be connected to low energy phonons, while at TB the Na ion diffusion suddenly gets fast enough, and the characteristic signal of quasielastic scattering appears. The current results further elucidate the subtle changes in the Na ion dynamics that have been revealed in our previous neutron diffraction studies [1], intimately connecting structural transformations at TA and TB with the opening-up of 1D and 2D Na-ion diffusion paths. Finally, the estimated diffusion coefficient above TB was found to differ from the one measured by muon- spin relaxation (mu(+) SR) [2] by about four orders of magnitude. However it might be that the present QENS data rather describe a fast localized prozess than a long range translational diffusion. Within this model the corresponding time scale (h/E) would be in the order of 50 ps.

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Type
conference paper
DOI
10.1051/epjconf/20158302008
Web of Science ID

WOS:000351844900010

Author(s)
Juranyi, Fanni
Mansson, Martin  
Gavilano, Jorge L.
Mena, Mattia
Pomjakushina, Ekaterina
Medarde, Marisa
Sugiyama, Jun
Kamazawa, Kazuya
Batlogg, Bertram
Ott, Hans R.
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Editors
Frick, B
•
Koza, Mm
•
Boehm, M
•
Mutka, H
Date Issued

2015

Publisher

E D P Sciences

Publisher place

Cedex A

Published in
Qens/Wins 2014 - 11Th International Conference On Quasielastic Neutron Scattering And 6Th International Workshop On Inelastic Neutron Spectrometers
Total of pages

5

Series title/Series vol.

EPJ Web of Conferences

Volume

83

URL

URL

http://lqm.epfl.ch/
Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LQM  
Event nameEvent placeEvent date
11th International Conference on Quasielastic Neutron Scattering / 6th International Workshop on Inelastic Neutron Spectrometers (QENS/WINS)

Autrans, FRANCE

MAY 11-16, 2014

Available on Infoscience
May 29, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/114479
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