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  4. Slow cooling and highly efficient extraction of hot carriers in colloidal perovskite nanocrystals
 
research article

Slow cooling and highly efficient extraction of hot carriers in colloidal perovskite nanocrystals

Li, Mingjie
•
Bhaumik, Saikat
•
Goh, Teck Wee
Show more
2017
Nature Communications

Hot-carrier solar cells can overcome the Schottky-Queisser limit by harvesting excess energy from hot carriers. Inorganic semiconductor nanocrystals are considered prime candidates. However, hot-carrier harvesting is compromised by competitive relaxation pathways (for example, intraband Auger process and defects) that overwhelm their phonon bottlenecks. Here we show colloidal halide perovskite nanocrystals transcend these limitations and exhibit around two orders slower hot-carrier cooling times and around four times larger hot-carrier temperatures than their bulk-film counterparts. Under low pump excitation, hot-carrier cooling mediated by a phonon bottleneck is surprisingly slower in smaller nanocrystals (contrasting with conventional nanocrystals). At high pump fluence, Auger heating dominates hot-carrier cooling, which is slower in larger nanocrystals (hitherto unobserved in conventional nanocrystals). Importantly, we demonstrate efficient room temperature hot-electrons extraction (up to similar to 83%) by an energy-selective electron acceptor layer within 1 ps from surface-treated perovskite NCs thin films. These insights enable fresh approaches for extremely thin absorber and concentrator-type hot-carrier solar cells.

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Type
research article
DOI
10.1038/ncomms14350
Web of Science ID

WOS:000393518000001

Author(s)
Li, Mingjie
Bhaumik, Saikat
Goh, Teck Wee
Kumar, Muduli Subas
Yantara, Natalia
Graetzel, Michael  
Mhaisalkar, Subodh
Mathews, Nripan
Sum, Tze Chien
Date Issued

2017

Publisher

Nature Publishing Group

Published in
Nature Communications
Volume

8

Article Number

14350

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
March 27, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/135876
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