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research article

Confinement-Controlled Water Engenders Unusually High Electrochemical Capacitance

Melnik, Svetlana
•
Ryzhov, Alexander
•
Kiselev, Alexei
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July 17, 2023
The Journal of Physical Chemistry Letters

The electrodynamicsof nanoconfined water have been shownto changedramatically compared to bulk water, opening room for safe electrochemicalsystems. We demonstrate a nanofluidic "water-only" batterythat exploits anomalously high electrolytic properties of pure waterat firm confinement. The device consists of a membrane electrode assemblyof carbon-based nanomaterials, forming continuously interconnectedwater-filled nanochannels between the separator and electrodes. Theefficiency of the cell in the 1-100 nm pore size range showsa maximum energy density at 3 nm, challenging the region of the currentmetal-ion batteries. Our results establish the electrodynamic fundamentalsof nanoconfined water and pave the way for low-cost and inherentlysafe energy storage solutions that are much needed in the renewableenergy sector.

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Type
research article
DOI
10.1021/acs.jpclett.3c01498
Web of Science ID

WOS:001027361000001

Author(s)
Melnik, Svetlana
•
Ryzhov, Alexander
•
Kiselev, Alexei
•
Radenovic, Aleksandra  
•
Weil, Tanja
•
Stevenson, Keith J.
•
Artemov, Vasily G.
Date Issued

2023-07-17

Publisher

AMER CHEMICAL SOC

Published in
The Journal of Physical Chemistry Letters
Subjects

Chemistry, Physical

•

Nanoscience & Nanotechnology

•

Materials Science, Multidisciplinary

•

Physics, Atomic, Molecular & Chemical

•

Chemistry

•

Science & Technology - Other Topics

•

Materials Science

•

Physics

•

supercapacitor electrodes

•

graphene

•

transport

•

friction

•

slippage

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LBEN  
Available on Infoscience
July 31, 2023
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/199549
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