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  4. Generalized Synthesis to Produce Transparent Thin Films of Ternary Metal Oxide Photoelectrodes
 
research article

Generalized Synthesis to Produce Transparent Thin Films of Ternary Metal Oxide Photoelectrodes

Lhermitte, Charles R.  
•
Polo, Annalisa
•
Yao, Liang  
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June 4, 2020
Chemsuschem

Developing facile approaches to prepare non-light-scattering ternary oxide thin film photoelectrodes is an important goal for solar water splitting tandem cells. Herein, a novel synthesis route is reported that employs ethylenediaminetetraacetic acid (EDTA) to enable compatible water solubility of diverse metal cations, which affords transparent films by solution processing. By using BiVO4 as a model material, a remarkable improvement in transparency is demonstrated, quantified by the direct transmittance at 600 nm of >80 % versus the <10 % observed with state-of-the-art electrodeposited thin films while maintaining reasonable solar-driven oxidation photocurrents (1.75 mA cm(-2) in the presence of a sulfite hole scavenger). Furthermore, it is demonstrated that the synthesis technique can be applied in a general fashion towards the synthesis of diverse n- and p-type metal oxide materials, such as ZnFe2O4 and CuFeO2.

  • Details
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Type
research article
DOI
10.1002/cssc.202000926
Web of Science ID

WOS:000537584300001

Author(s)
Lhermitte, Charles R.  
Polo, Annalisa
Yao, Liang  
Boudoire, Florent A.
Guijarro, Nestor  
Sivula, Kevin  
Date Issued

2020-06-04

Publisher

WILEY-V C H VERLAG GMBH

Published in
Chemsuschem
Volume

13

Issue

14

Start page

3645

End page

3653

Subjects

Chemistry, Multidisciplinary

•

Green & Sustainable Science & Technology

•

Chemistry

•

Science & Technology - Other Topics

•

metal oxides

•

photoelectrochemistry

•

solar water splitting

•

sol-gel

•

spray pyrolysis

•

bivo4 photoanodes

•

water

•

performance

•

chemistry

•

acid

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LIMNO  
Available on Infoscience
June 18, 2020
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/169401
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