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  4. Highly enantio- and diastereoselective inverse electron demand hetero-Diels-Alder reaction
 
conference paper

Highly enantio- and diastereoselective inverse electron demand hetero-Diels-Alder reaction

Jacobsen, Eric N.
•
Chavez, David E.
•
Gademann, Karl  
2002
Abstracts of Papers, 224th ACS National Meeting, Boston, MA, United States, August 18-22, 2002

A highly enantioselective and diastereoselective inverse electron demand hetero-Diels-Alder reaction between a variety of alpha,beta-unsatd. aldehydes and Et vinyl ether is described. The reaction is catalyzed by a chiral tridentate chromium(III) Schiff base complex, which is obtained by a concise and highly efficient protocol in two steps from com. materials. The resulting cycloadducts are isolated in good yields and are useful synthetic intermediates. [on SciFinder (R)]

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Type
conference paper
Author(s)
Jacobsen, Eric N.
Chavez, David E.
Gademann, Karl  
Date Issued

2002

Published in
Abstracts of Papers, 224th ACS National Meeting, Boston, MA, United States, August 18-22, 2002
Start page

ORGN

End page

411

Note

FIELD Section Title:

Department of Chemistry and Chemical Biology,Harvard University,Cambridge,MA,USA. FIELD URL:

written in English.

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LSYNC  
Available on Infoscience
November 22, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/235830
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