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research article

Polarity of translation boundaries in antiferroelectric PbZrO3

Wei, Xian-Kui
•
Jia, Chun-Lin
•
Roleder, Krystian
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2015
Materials Research Bulletin

The polarity of translation boundaries (TBs) in antiferroelectric PbZrO3 is investigated. We show that previous experimentally reported polar property of RIII-1 type TB can be well approximated by a strain-free rigid model. Based on this, the modeling investigation suggests that there are two additional polar TBs, three antipolar-like TBs and one antipolar antiphase boundary. High-resolution scanning-transmission-electron-microscopy study reveals that the straight RIII-1 type TB can split into "sub-domains" with possible polarization reversal, suggesting the occurrence of ferroic orders at the TBs. In addition, dependence of morphology and density of the TBs on thermal treatments is discussed according to our results. (C) 2014 Published by Elsevier Ltd.

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Type
research article
DOI
10.1016/j.materresbull.2014.11.024
Web of Science ID

WOS:000347762300015

Author(s)
Wei, Xian-Kui
Jia, Chun-Lin
Roleder, Krystian
Setter, Nava  
Date Issued

2015

Publisher

Pergamon-Elsevier Science Ltd

Published in
Materials Research Bulletin
Volume

62

Start page

101

End page

105

Subjects

Structural materials

•

Microstructure

•

Transmission electron microscopy (TEM)

•

Defects

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LC  
Available on Infoscience
February 20, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/111252
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