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research article

Scaling Printable Zn-Ag2O Batteries for Integrated Electronics

Kumar, Rajan
•
Johnson, Kevin M.
•
Williams, Nicholas X.
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April 4, 2019
Advanced Energy Materials

Printed batteries are an emerging solution for integrated energy storage using low-cost, high accuracy fabrication techniques. While several printed batteries have been previously shown, few have designed a battery that can be incorporated into an integrated device. Specifically, a fully printed battery with a small active electrode area (<1 cm(2)) achieving high areal capacities (>10 mAh cm(-2)) at high current densities (1-10 mA cm(-2)) has not been demonstrated, which represents the minimum form-factor and performance requirements for many low-power device applications. This work addresses these challenges by investigating the scaling limits of a fully printed Zn-Ag2O battery and determining the electrochemical limitations for a mm(2)-scale battery. Processed entirely in air, Zn-Ag2O batteries are well suited for integration in typical semiconductor packaging flows compared to lithium-based chemistries. Printed cells with electrodes as small as 1 mm(2) maintain steady operating voltages above (>1.4 V) at high current densities (1-12 mA cm(-2)) and achieve the highest reported areal capacity for a fully printed battery at 11 mAh cm(-2). The findings represent the first demonstration of a small, packaged, fully printed Zn-Ag2O battery with high areal capacities at high current densities, a crucial step toward realizing chip-scale energy storage for integrated electronic systems.

  • Details
  • Metrics
Type
research article
DOI
10.1002/aenm.201803645
Web of Science ID

WOS:000467131300007

Author(s)
Kumar, Rajan
Johnson, Kevin M.
Williams, Nicholas X.
Subramanian, Vivek  
Date Issued

2019-04-04

Publisher

WILEY-V C H VERLAG GMBH

Published in
Advanced Energy Materials
Volume

9

Issue

13

Article Number

1803645

Subjects

Chemistry, Physical

•

Energy & Fuels

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Materials Science, Multidisciplinary

•

Physics, Applied

•

Physics, Condensed Matter

•

Chemistry

•

Materials Science

•

Physics

•

high areal capacity

•

integrated devices

•

printed batteries

•

sol-gel separators

•

etch rates

•

alkaline

•

challenges

•

optimization

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oxide

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LAFT  
Available on Infoscience
June 18, 2019
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/157351
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