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  4. Active microrheology in corrugated channels: Comparison of thermal and colloidal baths
 
research article

Active microrheology in corrugated channels: Comparison of thermal and colloidal baths

Malgaretti, Paolo
•
Puertas, Antonio M.
•
Pagonabarraga, Ignacio  
February 15, 2022
Journal Of Colloid And Interface Science

Hypothesis: The dynamics of colloidal suspension confined within porous materials strongly differs from that in the bulk. In particular, within porous materials, the presence of boundaries with complex shapes entangles the longitudinal and transverse degrees of freedom inducing a coupling between the transport of the suspension and the density inhomogeneities induced by the walls. Method: Colloidal suspension confined within model porous media are characterized by means of active microrheology where a net force is applied on a single colloid (tracer particle) whose transport properties are then studied. The trajectories provided by active microrheology are exploited to determine the local transport coefficients. In order to asses the role of the colloid-colloid interactions we compare the case of a tracer embedded in a colloidal suspension to the case of a tracer suspended in an ideal bath. Finding: Our results show that the friction coefficient increases and the passage time distribution widens upon increasing the corrugation of the channel. These features are obtained for a tracer suspended in a (thermalized) colloidal bath as well as for the case of an ideal thermal bath. These results highlight the relevance of the confinement on the transport and show a mild dependence on the colloidal/thermal bath. Finally, we rationalize our numerical results with a semi-analytical model. Interestingly, the predictions of the model are quantitatively reliable for mild external forces, hence providing a reliable tool for predicting the transport across porous materials. (c) 2021 Elsevier Inc. All rights reserved.

  • Details
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Type
research article
DOI
10.1016/j.jcis.2021.10.193
Web of Science ID

WOS:000768787700005

Author(s)
Malgaretti, Paolo
Puertas, Antonio M.
Pagonabarraga, Ignacio  
Date Issued

2022-02-15

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE

Published in
Journal Of Colloid And Interface Science
Volume

608

Start page

2694

End page

2702

Subjects

Chemistry, Physical

•

Chemistry

•

active microrheology

•

porous materials

•

entropic barriers

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
ISIC-GE  
Available on Infoscience
April 11, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/187059
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