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research article

Characterization of frequency-dependent glass transition temperature by Vogel-Fulcher relationship

Bai, Yu  
•
Jin, Li
2008
Journal of Physics D-Applied Physics

The complex mechanical modulus of polymer and polymer based composite materials showed a frequency-dependent behaviour during glass transition relaxation, which was historically modelled by the Arrhenius equation. However, this might not be true in a broad frequency domain based on the experience from the frequency dependence of the complex dielectric permittivity, which resulted from the same glass transition relaxation as for the complex mechanical modulus. Considering a good correspondence between dielectric and mechanical relaxation during glass transition, the Vogel-Fulcher relationship, previously proposed for the frequency dependence of dielectric permittivity, is introduced for that of the mechanical modulus; and the corresponding static glass transition temperature (T-f) was first determined for polymer and polymer based composite materials.

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Type
research article
DOI
10.1088/0022-3727/41/15/152008
Web of Science ID

WOS:000257839700008

Author(s)
Bai, Yu  
Jin, Li
Date Issued

2008

Published in
Journal of Physics D-Applied Physics
Volume

41

Issue

15

Article Number

152008

Subjects

Band Dielectric-Spectroscopy

•

Dynamic-Mechanical Analysis

•

Composites

•

Relaxation

•

Viscosity

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
CCLAB  
Available on Infoscience
November 30, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/61161
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