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  4. Sodium Superionic Conductors (NASICONs) as Cathode Materials for Sodium-Ion Batteries
 
review article

Sodium Superionic Conductors (NASICONs) as Cathode Materials for Sodium-Ion Batteries

Zhou, Qingbo
•
Wang, Linlin
•
Li, Wenyao
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September 8, 2021
Electrochemical Energy Reviews

Sodium-ion batteries (SIBs) have developed rapidly owing to the high natural abundance, wide distribution, and low cost of sodium. Among the various materials used in SIBs, sodium superion conductor (NASICON)-based electrode materials with remarkable structural stability and high ionic conductivity are one of the most promising candidates for sodium storage electrodes. Nevertheless, the relatively low electronic conductivity of these materials makes them display poor electrochemical performance, significantly limiting their practical application. In recent years, the strategies of enhancing the inherent conductivity of NASICON-based cathode materials have been extensively studied through coating the active material with a conductive carbon layer, reducing the size of the cathode material, combining the cathode material with various carbon materials, and doping elements in the bulk phase. In this paper, we review the recent progress in the development of NASICON-based cathode materials for SIBs in terms of their synthesis, characterization, functional mechanisms, and performance validation/optimization. The advantages and disadvantages of such SIB cathode materials are analyzed, and the relationship between electrode structures and electrochemical performance as well as the strategies for enhancing their electrical conductivity and structural stability is highlighted. Some technical challenges of NASICON-based cathode materials with respect to SIB performance are analyzed, and several future research directions are also proposed for overcoming the challenges toward practical applications.

  • Details
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Type
review article
DOI
10.1007/s41918-021-00120-8
Web of Science ID

WOS:000695740700001

Author(s)
Zhou, Qingbo
Wang, Linlin
Li, Wenyao
Zhao, Kangning  
Liu, Minmin
Wu, Qian
Yang, Yujie
He, Guanjie
Parkin, Ivan P.
Shearing, Paul R.
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Date Issued

2021-09-08

Publisher

SPRINGERNATURE

Published in
Electrochemical Energy Reviews
Volume

4

Start page

793

End page

823

Subjects

Electrochemistry

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sodium-ion battery

•

cathode materials

•

energy storage

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sodium superionic conductor (nasicon)

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high-rate performance

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carbon-coated na3v2(po4)(3)

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electrical energy-storage

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high-voltage cathode

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high-rate capability

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life-span cathode

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electrochemical performance

•

long-life

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high-power

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3-dimensional graphene

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LAS  
Available on Infoscience
September 25, 2021
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/181720
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