Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Expansion mechanisms in calcium aluminate and sulfoaluminate systems with calcium sulfate
 
research article

Expansion mechanisms in calcium aluminate and sulfoaluminate systems with calcium sulfate

Bizzozero, Julien  
•
Gosselin, Christophe  
•
Scrivener, Karen L.  
2014
Cement and Concrete Research

The long-term expansion of calcium aluminate cement and calcium sulfoaluminate cement in the presence of added gypsum has been studied for samples cured under water. Progressively higher amounts of gypsum were added to the CAC or CSA and it was found that there is a critical amount of gypsum leading to unstable expansion and failure of the samples. The microstructures of systems with gypsum additions just below and above the threshold were similar. Pore solution analyses showed that supersaturation with respect to ettringite increases with the calcium sulfate content, which results in an increase of the crystallization pressure. The supersaturation determines the minimum pore size in which crystals can grow. Therefore with higher supersaturation a larger pore volume is accessible to growing ettringite crystals exerting pressure in the porous skeleton. This could explain the critical amount of gypsum leading to high unstable expansion. (C) 2013 Elsevier Ltd. All rights reserved.

  • Details
  • Metrics
Type
research article
DOI
10.1016/j.cemconres.2013.11.011
Web of Science ID

WOS:000331424500020

Author(s)
Bizzozero, Julien  
Gosselin, Christophe  
Scrivener, Karen L.  
Date Issued

2014

Publisher

Pergamon-Elsevier Science Ltd

Published in
Cement and Concrete Research
Volume

56

Start page

190

End page

202

Subjects

Crystal size

•

Pore solution

•

Stability

•

Ettringite

•

Crystallization pressure

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LMC  
Available on Infoscience
April 2, 2014
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/102422
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés