Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Formation of electron traps in semiconducting polymers via a slow triple-encounter between trap precursor particles
 
research article

Formation of electron traps in semiconducting polymers via a slow triple-encounter between trap precursor particles

Sedghi, Mohammad
•
Vael, Camilla
•
Hu, Wei-Hsu  
Show more
December 31, 2024
Science And Technology Of Advanced Materials

Already in 2012, Blom et al. reported (Nature Materials 2012, 11, 882) in semiconducting polymers on a general electron-trap density of approximate to 3 x 10(17) cm(-3), centered at an energy of approximate to 3.6 eV below vacuum. It was suggested that traps have an extrinsic origin, with the water-oxygen complex [2(H2O)-O-2] as a possible candidate, based on its electron affinity. However, further evidence is lacking and the origin of universal electron traps remained elusive. Here, in polymer diodes, the temperature-dependence of reversible electron traps is investigated that develop under bias stress slowly over minutes to a density of 2 x 10(17) cm(-3), centered at an energy of 3.6 eV below vacuum. The trap build-up dynamics follows a 3(rd)-order kinetics, in line with that traps form via an encounter between three diffusing precursor particles. The accordance between universal and slowly evolving traps suggests that general electron traps in semiconducting polymers form via a triple-encounter process between oxygen and water molecules that form the suggested [2(H2O)-O-2] complex as the trap origin.

  • Details
  • Metrics
Type
research article
DOI
10.1080/14686996.2024.2312148
Web of Science ID

WOS:001162684300001

Author(s)
Sedghi, Mohammad
Vael, Camilla
Hu, Wei-Hsu  
Bauer, Michael
Padula, Daniele
Landi, Alessandro
Lukovic, Mirko
Diethelm, Matthias
Wetzelaer, Gert-Jan
Blom, Paul W. M.
Show more
Date Issued

2024-12-31

Published in
Science And Technology Of Advanced Materials
Volume

25

Issue

1

Article Number

2312148

Subjects

Technology

•

Polymer Light-Emitting Diodes

•

Electron Trap

•

Charge Trap Dynamics

•

Device Physics

•

Semiconducting Polymer

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
UPNUES  
FunderGrant Number

Italian MUR, Rita Levi Montalcini

PGR18PJMBW

Schweizerischer Nationalfonds zur Foerderung der Wissenschaftlichen Forschung

IZBRZ2_186261

Available on Infoscience
March 18, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/206397
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés