Publication:

Ein einfacher und allgemeiner Zugang zu 2-Fluor-1,3-dienen

cris.lastimport.scopus

2025-06-03T18:32:44Z

cris.legacyId

81533

cris.virtual.sciperId

123541

cris.virtual.unitManager

Schlosser, Manfred

cris.virtualsource.author-scopus

b5021598-2db9-478e-8f9b-c1cf1bc36207

cris.virtualsource.department

b5021598-2db9-478e-8f9b-c1cf1bc36207

cris.virtualsource.orcid

b5021598-2db9-478e-8f9b-c1cf1bc36207

cris.virtualsource.parent-organization

d56f1401-ce26-4bc7-833f-139df449613b

cris.virtualsource.rid

b5021598-2db9-478e-8f9b-c1cf1bc36207

cris.virtualsource.sciperId

b5021598-2db9-478e-8f9b-c1cf1bc36207

cris.virtualsource.unitId

d56f1401-ce26-4bc7-833f-139df449613b

cris.virtualsource.unitManager

d56f1401-ce26-4bc7-833f-139df449613b

datacite.rights

metadata-only

dc.contributor.author

Spahic, Bojana

dc.contributor.author

Truong Thi My, Thu

dc.contributor.author

Schlosser, Manfred

dc.date.accessioned

2006-03-03T14:11:41

dc.date.available

2006-03-03T14:11:41

dc.date.created

2006-03-03

dc.date.issued

1980

dc.date.modified

2024-10-17T23:08:38.339738Z

dc.description.abstract

Fluoroalkadienes were prepd. by Zn-catalyzed ring cleavage of 1-chloro-1-fluoro-2-halomethylcyclopropanes, obtained by treating haloalkenes with FCHCl2. Thus, ClCH2CH:CMeEt was treated with FCHCl2 to give the cyclopropane I (R = Cl) which was iodinated to give I (R = iodo). Treatment of the latter compd. with Zn gave CH2:CHCF:CMeEt. The fluorocycloheptadiene II was similarly obtained. [on SciFinder (R)]

dc.description.notes

CAN 93:220354

dc.description.notes

23-3

dc.description.notes

Aliphatic Compounds

dc.description.notes

Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.

dc.description.notes

Journal

dc.description.notes

written in German.

dc.description.notes

21378-21-2 Role: RCT (Reactant), RACT (Reactant or reagent) (acetylation of); 75411-52-8P; 75411-53-9P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and bromination of); 75411-50-6P; 75411-51-7P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and deacetylation of); 75411-39-1P; 75411-40-4P; 75411-45-9P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and iodination of); 75411-49-3P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and reaction of, with fluorodichloromethane); 75411-69-7P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and reaction of, with tetracyanoethylene); 75411-58-4P; 75521-28-7P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and redn. of); 75411-43-7P; 75411-44-8P; 75411-46-0P; 75411-54-0P; 75411-55-1P; 75411-56-2P; 75411-57-3P; 75411-63-1P; 75411-64-2P; 75411-65-3P; 75411-66-4P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and ring cleavage of); 51954-22-4P; 56620-29-2P; 56649-99-1P; 75411-41-5P; 75411-42-6P; 75411-47-1P; 75411-48-2P; 75411-59-5P; 75411-60-8P; 75411-61-9P; 75411-62-0P; 75411-67-5P; 75411-68-6P; 75411-70-0P; 75411-71-1P; 75422-90-1P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of); 503-60-6 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with dichlorofluoromethane); 870-63-3 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with dichlorofluromethane); 591-49-1; 1937-03-7; 37866-06-1 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with fluorodichloromethane); 670-54-2 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with fluoromethylcycloheptadiene); 75-43-4 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with haloalkenes)

dc.description.sponsorship

LSCO

dc.identifier.doi

10.1002/hlca.19800630515

dc.identifier.uri

https://infoscience.epfl.ch/handle/20.500.14299/226793

dc.relation.issn

0018-019X

dc.relation.journal

Helvetica Chimica Acta

dc.subject

fluoroalkadiene; alkadiene fluoro; cycloalkadiene fluoro; halocyclopropane prepn ring cleavage

dc.title

Ein einfacher und allgemeiner Zugang zu 2-Fluor-1,3-dienen

dc.type

text::journal::journal article::research article

dspace.entity.type

Publication

dspace.legacy.oai-identifier

oai:infoscience.tind.io:81533

epfl.legacy.itemtype

Journal Articles

epfl.legacy.submissionform

ARTICLE

epfl.oai.currentset

SB

epfl.oai.currentset

OpenAIREv4

epfl.oai.currentset

article

epfl.peerreviewed

REVIEWED

epfl.publication.version

http://purl.org/coar/version/c_970fb48d4fbd8a85

epfl.writtenAt

EPFL

oaire.citation.endPage

1241

oaire.citation.issue

5

oaire.citation.startPage

1236

oaire.citation.volume

63

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