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research article

Local electrochemical and thermal investigation of a segmented reversible solid oxide fuel cell and electrolyzer

Moussaoui, H.
•
Wesoly, Audrey Désirée  
•
Diethelm, S.  
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December 16, 2023
Electrochimica Acta

A novel setup has been designed and mounted to investigate the local electrochemical and thermal behavior of a cell from a 4-cell short stack under reversible operation solid oxide fuel cell/solid oxide electrolyzer (SOFC/SOE). It consists in the partition of the cell's oxygen electrode into 20 segments, where each segment is controlled by a specific electronic load. This allows to control the segments independently in galvanostatic or potentiostatic mode. The configuration also enables local electrochemical impedance spectroscopy (EIS) measurements of each segment. 20 thermocouples were added to measure the local temperature of the segments in order to gain a deeper insight into the cell thermal distribution. This helps correlating the local thermal and electrochemical responses to the operating parameters. This specific setup allowed mapping the cell's local behavior based on a multidimensional operating conditions matrix, including current density, temperature, feed gas composition, sweep gas flow and polarization. Moreover, a durability test of more than 1,000 h helped investigating the local long-term degradation in a reversible (day SOE, night SOFC) configuration. These results are of significant importance towards optimal operation of a reversible SOC with enhanced durability.

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Type
research article
DOI
10.1016/j.electacta.2023.143627
Web of Science ID

WOS:001136044900001

Author(s)
Moussaoui, H.
Wesoly, Audrey Désirée  
Diethelm, S.  
Wuillemin, Z.
Montinaro, D.
Van Herle, J  
Date Issued

2023-12-16

Publisher

Pergamon-Elsevier Science Ltd

Published in
Electrochimica Acta
Volume

475

Article Number

143627

Subjects

Physical Sciences

•

Reversible Solid Oxide Fuel Cell And Electrolyzer

•

Segmented Cell

•

Electrochemical Impedance Spectroscopy

•

Durability Test

•

Soc Degradation

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
SCI-STI-JVH  
FunderGrant Number

Fuel Cells and Hydrogen Joint Undertaking

875047

European Union

Available on Infoscience
February 20, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/204888
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