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  4. Adsorption of amphiphilic grafted polymers as polymer corrosion inhibitors: insights from mesoscopic simulations
 
research article

Adsorption of amphiphilic grafted polymers as polymer corrosion inhibitors: insights from mesoscopic simulations

Diaz, Javier
•
Soltau, Marko
•
Lisal, Martin
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May 3, 2022
Physical Chemistry Chemical Physics

The homogeneous covering of amphiphillic polymer molecules onto metallic surfaces is of great importance for corrosion inhibitor applications. Lyophillic side chains grafted onto a lyophobic backbone act as anchors that allow the molecule to absorb at the metallic surface preventing the exposure with the solvent. Coarse-grained simulations are used to study the sorption and conformation behaviour of amphiphillic grafted polymers for corrosion inhibition. The backbone insolubility is found to play a key role in the sorption and conformation behaviour in the dilute limit. For finite concentrations, moderate backbone solubility and moderate molecule concentrations achieve optimal surface coverage, while highly a lyophobic backbone leads to bulk-like structures as a consequence of aggregation.

  • Details
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Type
research article
DOI
10.1039/d2cp00504b
Web of Science ID

WOS:000792344100001

Author(s)
Diaz, Javier
Soltau, Marko
Lisal, Martin
Carbone, Paola
Pagonabarraga, Ignacio  
Date Issued

2022-05-03

Publisher

ROYAL SOC CHEMISTRY

Published in
Physical Chemistry Chemical Physics
Volume

24

Issue

19

Start page

11992

End page

12001

Subjects

Chemistry, Physical

•

Physics, Atomic, Molecular & Chemical

•

Chemistry

•

Physics

•

dissipative particle dynamics

•

diblock copolymer

•

selective solvents

•

drug nanoparticles

•

chromatography

•

stiffness

•

coatings

•

behavior

•

brushes

•

surface

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
ISIC-GE  
Available on Infoscience
May 23, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/188109
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