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  4. Photonic Processing of MAPbI(3) Films by Flash Annealing and Rapid Growth for High-Performance Perovskite Solar Cells
 
research article

Photonic Processing of MAPbI(3) Films by Flash Annealing and Rapid Growth for High-Performance Perovskite Solar Cells

Serafini, Patricio
•
Boix, Pablo P.
•
Barea, Eva M.
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October 25, 2022
Solar Rrl

Defects in polycrystalline halide perovskite films can cause a decrease of the solar cell photoconversion efficiency and stability. The perovskite film enhanced during crystal growth by controlling the processing method can alleviate defects and the related recombination sites that affect the performance of cells. Herein, flash infrared annealing is employed to crystallize methylammonium lead iodide perovskite with a single heating pulse, where uniform grain domains are optically observed and mapped. Films are annealed with different temperature ramps up to 48 degrees C s(-1) heating rate. Annealing with higher heating rates presents lower defect densities, decreases the Urbach energy tail, and improves the optoelectrical performance of the films. These improvements are rationalized by Raman spectroscopy of nucleation points and grain surface differences among the process variations. The role of crystal growth and subsequent film quality allows to achieve a champion photovoltaic device growth at 48 degrees C s(-1) with stability around 250 h under 1 sun illumination and 60% relative humidity for 100 h under 3 sun (AM1.5G) illumination. In situ optical imaging is recorded during the process, confirming that rapid annealing, i.e., higher heating rates, contributes to obtain more stable devices with the added advantage of shorter processing time.

  • Details
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Type
research article
DOI
10.1002/solr.202200641
Web of Science ID

WOS:000875913300001

Author(s)
Serafini, Patricio
Boix, Pablo P.
Barea, Eva M.
Edvinson, Tomas
Sanchez, Sandy  
Mora-Sero, Ivan
Date Issued

2022-10-25

Published in
Solar Rrl
Article Number

2200641

Subjects

Energy & Fuels

•

Materials Science, Multidisciplinary

•

Energy & Fuels

•

Materials Science

•

crystal growth

•

defects

•

flash infrared annealing

•

perovskites

•

processing

•

stability

•

open-circuit voltage

•

thin-films

•

surface-defects

•

temperature

•

ch3nh3pbi3

•

crystallization

•

recombination

•

morphology

•

degradation

•

evolution

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
ISIC  
RelationURL/DOI

IsReviewedBy

https://infoscience.epfl.ch/record/300486
Available on Infoscience
November 21, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/192448
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