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research article

Fourier transform spectroscopy in the vibrational fingerprint region with a birefringent interferometer

Réhault, J
•
Borrego-Varillas, R
•
Oriana, A
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2017
Optics Express

We introduce a birefringent interferometer for Fourier transform (FT) spectroscopy in the mid-infrared, covering the vibrational fingerprint region (5-10 µm, 1000-2000 cm<sup>-1</sup>), which is crucial for molecular identification. Our interferometer employs the crystal calomel (Hg<sub>2</sub>Cl<sub>2</sub>), which combines high birefringence (n<sub>e</sub>-n<sub>o</sub>≈0.55) with a broad transparency range (0.38-20 µm). We adopt a design based on birefringent wedges, which is simple and compact and guarantees excellent delay accuracy and long-term stability. We demonstrate FTIR spectroscopy, with a frequency resolution of 3 cm<sup>-1</sup>, as well as two-dimensional IR (2DIR) spectroscopy. Our setup can be extended to other spectroscopic modalities such as vibrational circular dichroism and step-scan FT spectroscopy.

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Type
research article
DOI
10.1364/Oe.25.004403
Web of Science ID

WOS:000397317400135

Author(s)
Réhault, J
•
Borrego-Varillas, R
•
Oriana, A
•
Manzoni, C
•
Hauri, C P  
•
Helbing, J
•
Cerullo, G
Date Issued

2017

Publisher

Optical Society of America

Published in
Optics Express
Volume

25

Issue

4

Start page

4403

End page

4413

Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
GR-HAU  
Available on Infoscience
April 17, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/136518
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