Troelstra, E. J.Dierendonck, L. L. V.Janssen, L. P. B. M.Maeder, S.Renken, A.2006-04-182006-04-182006-04-18199610.1016/0009-2509(96)00105-4https://infoscience.epfl.ch/handle/20.500.14299/229419WOS:A1996UK96000088The radical addn. co-polymn. of 2-hydroxyethyl methacrylate and Bu acrylate is carried out in a continuously operating Buss-Kneader. To calc. temp. profiles over the length of the kneader the heat balance is solved. For the heat transfer coeff. a model based on the penetration theory is used. This model is exptl. verified. The reaction kinetics of the radical addn. polymn. are studied in a differential scanning calorimeter. The polymn. kinetics are modeled using non-stationary radical concns. The calcd. temp. profiles over the length of the Buss-Kneader are a good approxn. of the exptl. data. [on SciFinder (R)]Polymerization catalysts (benzoyl peroxide; radical polymn. of Bu acrylate with hydroxyethyl methacrylate in Buss-Kneader); Kinetics of polymerization (kinetics of radical polymn. of Bu acrylate with hydroxyethyl methacrylate in Buss-Kneader)polymn hydroxyethyl methacrylate butyl acrylate; kinetics polymn methacrylate acrylatetext::journal::journal article::research article